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Small-molecular mass porphyrins in which a carboxylic acid group replaces the chlorine atom in TPPH have been prepared. The molecular masses of these compounds were determined by читать полностью spectroscopy, нажмите для продолжения their structure was confirmed by single-crystal X-ray diffraction.
The porphyrins have been used to determine the excitation spectra of TPPH and its isomeric porphyrins. Spectral measurements were performed by flash photolysis, steady-state absorption, and steady-state fluorescence. The excitation spectra of all the porphyrins form a continuum, with the fluorescence maximized at approximately nm.
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